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008 130510s2013 nju ob 001 0 eng
010 _a 2013019308
020 _a9781118690680 (pdf)
020 _a1118690680 (pdf)
020 _a9781118690475 (epub)
020 _a1118690478 (epub)
020 _a9781118690505 ( mobi)
020 _a1118690508 ( mobi)
020 _z9781118060452 (hardback)
020 _a9781118690659
020 _a1118690656
020 _a1118060458
020 _a9781118060452
020 _a9781299939660
020 _a129993966X
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035 _a(OCoLC)843026114
_z(OCoLC)864918046
_z(OCoLC)876848244
040 _aDLC
_beng
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082 0 0 _a546/.652595
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084 _aSCI013050
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245 0 0 _aCopper-mediated cross-coupling reactions /
_cedited by Gwilherm Evano, Laboratoire de chimie organique, Service de chimie et physicochimie organiques, Université libre de Bruxelles, Brussels, Belgium, Nicolas Blanchard, Université de Strasbourg, École européenne de chimie, polymères et Matériaux, Laboratoire de chimie moléculaire associé au CNRS, Strasbourg, France.
_h[electronic resource]
264 1 _aHoboken, New Jersey :
_bWiley,
_c[2013]
300 _a1 online resource.
336 _atext
_2rdacontent
337 _acomputer
_2rdamedia
338 _aonline resource
_2rdacarrier
500 _aMachine generated contents note: Introduction Copper catalysis from an historical perspective: a legacy from the past Gwilherm Evano and Nicolas Blanchard PART 1 FORMATION OF C-HETEROATOM BONDS Chapter 1: Modern Ullmann-Goldberg Chemistry: Arylation of N-nucleophiles with Aryl Halides Yongwen Jiang and Dawei Ma Chapter 2: Ullmann condensation today: arylation of alcohols and thiols with aryl halides Anis Tlili and Marc Taillefer Chapter 3: Copper-Catalyzed Formation of C-P Bonds with Aryl Halides Carole Alayrac and Annie-Claude Gaumont Chapter 4: Alternative and Emerging Reagents for the Arylation of Heteronucleophiles Luc Neuville Chapter 5: Beyond Ullmann-Goldberg Chemistry: Vinylation, Alkynylation and Allenylation of Heteronucleophiles Kevin Jouvin and Gwilherm Evano Chapter 6: Aromatic/Vinylic Finkelstein Reaction Alicia Casitas and Xavi Ribas Chapter 7: Insights into the Mechanism of Modern Ullmann-Goldberg Coupling Reactions Alicia Casitas and Xavi Ribas PART 2 FORMATION OF C-C BONDS Chapter 8: Modern Copper-Catalyzed Hurtley Reaction: Efficient C-Arylation of CH-Acid Derivatives Irina P Beletskaya and Alexey Yu Fedorov Chapter 9: Copper-Catalyzed Cyanations of Aryl Halides and Related Compounds Thomas Schareina and Matthias Beller Chapter 10: Copper-Mediated Aryl-aryl Bond Formation Leading to Biaryls: A Century After Ullmann Breakthrough Yoshihiko Yamamoto Chapter 11: Copper-Catalyzed Alkynylation, Alkenylation and Allylation Reaction of Aryl Derivatives Ren-Jie Song and Jin-Heng Li Chapter 12: Copper-Catalyzed Alkynylation and Alkenylation Reaction of Alkynyl Derivatives: New Access to Diynes and Enynes Ruimao Hua Chapter 13: Copper-Mediated Alkenylation Reaction of Alkenyl Derivatives: a Straightforward Elaboration of 1,3-Dienes Hao Li, Songbai Liu, and Lanny S Liebeskind Chapter 14: Emerging Areas in Copper-Mediated Trifluoromethylations: Catalytic and Oxidative Cross-Coupling Processes Kevin Jouvin, Celine Guissart and Gwilherm Evano PART 3 APPLICATIONS OF COPPER CATALYZED CROSS COUPLING REACTIONS: HETEROCYCLES, NATURAL PRODUCTS, PROCESS AND SUSTAINABLE CHEMISTRY Chapter 15: Copper-Mediated Cyclization Reactions: New Entries to Heterocycles Daoshan Yang and Hua Fu Chapter 16: Copper-Mediated C-N Bond Forming Reactions: New Opportunities in Natural Product Synthesis Jihoon Lee and James S Panek Chapter 17: Natural Products and C-O/C-S Bond Forming Reactions: Copper Showed the Way Doron Pappo Chapter 18: Copper-Catalyzed C-C Bond Formation in Natural Product Synthesis: Elegant and Efficient Solutions to a Key Bond Disconnection Morgan Donnard and Nicolas Blanchard Chapter 19: Process Chemistry and Copper Catalysis Klaus Kunz and Norbert Lui Chapter 20: Reusable Catalysts for Copper-Mediated Coupling Reactions under Heterogeneous Conditions Zhiyong Wang, Changfeng Wan and Ye Wang .
504 _aIncludes bibliographical references and index.
505 0 _aTitle page; Copyright page; Foreword; Preface: Copper Catalysis from a Historical Perspective: A Legacy from the Past; The Historical and Remarkable First Discoveries by Fritz Ullmann and Irma Goldberg; Further Historical Developments: The Cyanation of Aryl Halides by Rosenmund and von Braun and the Arylation of Diketones and Malonates by Hurtley; From the Historical Discoveries to the Development of Modern Copper-Mediated Cross-Coupling Reactions; Modern Copper-Mediated Cross-Coupling Reactions and Their Impact in Organic Chemistry; Contributors; Part I: Formation of C-Heteroatom Bonds
505 8 _a1: Modern Ullmann-Goldberg Chemistry: Arylation of N-Nucleophiles with Aryl Halides1.1 Introduction; 1.2 Arylation of Amines; 1.3 Arylation of Amides, Imides, and Carbamates; 1.4 Arylation of Conjugated N-Heterocycles; 1.5 Synthesis of Anilines by Coupling with Ammonia or Synthetic Equivalents; 1.6 Conclusion and Future Prospects; 2: Ullmann Condensation Today: Arylation of Alcohols and Thiols with Aryl Halides; 2.1 Introduction; 2.2 Formation of C-O Bonds via Copper-Catalyzed Cross-Coupling Reactions with Aryl Halides
505 8 _a2.3 Formation of C-S Bonds via Copper-Catalyzed Cross-Coupling Reactions with Aryl Halides2.4 Conclusion; 3: Copper-Catalyzed Formation of C-P Bonds with Aryl Halides; 3.1 Introduction; 3.2 Arylation of Phosphines; 3.3 Arylation of Phosphine Oxides and Phosphites; 3.4 Conclusion; 4: Alternative and Emerging Reagents for the Arylation of Heteronucleophiles; 4.1 Introduction; 4.2 Chan-Lam-Evans Coupling: Copper(II)-Promoted Oxidative Aryl Transfer from Arylboron Derivatives; 4.3 Copper-Promoted Aryl Transfer from Metallated Aryl Derivatives (Nonboron)
505 8 _a4.4 Copper-Catalyzed Arylation Reactions Involving Masked S- and N-Nucleophiles4.5 Copper-Catalyzed Direct Heterofunctionalization of Aromatic C-H Bonds; 4.6 Conclusion and Future Prospects; 5: Beyond Ullmann-Goldberg Chemistry: Vinylation, Alkynylation, and Allenylation of Heteronucleophiles; 5.1 Introduction; 5.2 Copper-Mediated Alkenylation of Heteronucleophiles: Among the Best Routes to Heteroatom-Substituted Alkenes; 5.3 Alkynylation of Heteronucleophiles: The Emergence of General Methods for the Synthesis of Heteroatom-Substituted Alkynes
505 8 _a5.4 Allenylation of Heteronucleophiles: New Tools for the Synthesis of Allenamides5.5 Conclusion and Future Prospects; 6: Aromatic/Vinylic Finkelstein Reaction; 6.1 Introduction; 6.2 Copper-Mediated Halogen Exchange Reactions in Aryl Halides; 6.3 Most Recent Developments and Overview; 7: Insights into the Mechanism of Modern Ullmann-Goldberg Coupling Reactions; 7.1 General View and Key Mechanistic Aspects; 7.2 Oxidation State of Copper Catalysts; 7.3 Identity of the Active Copper(I) Complex; 7.4 Activation Mode of Aryl Halides by Copper Complexes
520 _a"Providing insight into the use of copper in cross-coupling reactions as a cost-efficient alternative to palladium, Copper-Mediated Cross Coupling Reactions provides a complete up-to-date collection of the available catalytic systems and processes. This essential reference covers a broad scope of copper-mediated reactions, their variations, key advances, improvements, and an array of applications that have revolutionized copper catalysis for any industry involving organic synthesis. The text discusses recently developed methods for conducting copper-mediated reactions with supported catalysts, which allow for recyclable and reusable systems"--
_cProvided by publisher.
520 _a"This book is divided into three parts: Formation of C-Heteroatom Bonds, Formation of C-C Bonds, and Applications of Copper Catalyzed Cross Coupling Reactions: Heterocycles, Natural Products, Process and Sustainable Chemistry"--
_cProvided by publisher.
588 _aDescription based on print version record and CIP data provided by publisher.
650 0 _aCopper catalysts.
650 0 _aCopper
_xReactivity.
650 0 _aChemical bonds.
650 0 _aOrganic compounds
_xSynthesis.
650 7 _aSCIENCE / Chemistry / Physical & Theoretical.
_2bisacsh
650 7 _aChemical bonds.
_2fast
_0(OCoLC)fst00852856
650 7 _aCopper catalysts.
_2fast
_0(OCoLC)fst00878447
650 7 _aCopper
_xReactivity.
_2fast
_0(OCoLC)fst00878394
650 7 _aOrganic compounds
_xSynthesis.
_2fast
_0(OCoLC)fst01047668
650 7 _aKatalysator.
_0(DE-588)4029919-3
_2gnd
650 7 _aKupfer.
_0(DE-588)4033734-0
_2gnd
650 7 _aKreuzkupplungsreaktion.
_0(DE-588)1033635499
_2gnd
650 7 _aOrganische Synthese.
_0(DE-588)4075695-6
_2gnd
655 4 _aElectronic books.
655 0 _aElectronic books.
700 1 _aEvano, Gwilherm,
_eeditor of compilation.
700 1 _aBlanchard, Nicolas,
_eeditor of compilation.
776 0 8 _iPrint version:
_tCopper-mediated cross-coupling reactions
_dHoboken, New Jersey : Wiley, [2013]
_z9781118060452
_w(DLC) 2013011111
856 4 0 _uhttp://onlinelibrary.wiley.com/book/10.1002/9781118690659
_zWiley Online Library
942 _2ddc
_cBK
999 _c206723
_d206723