05516cam a2200565Ii 4500 ocn956655956 OCoLC 20190328114816.0 m o d cr cnu---unuuu 160815s2016 nyua ob 001 0 eng d N$T eng rda pn N$T OPELS EBLCP UIU YDX CCO QCL OCLCQ OCLCO U3W D6H OCLCO 962437953 9780128019054 (electronic bk.) 0128019050 (electronic bk.) 9780128018941 0128018941 (OCoLC)956655956 (OCoLC)962437953 QD412.B1 SCI 013040 bisacsh 547/.05/671 22 Grimes, Russell N., 1935- author. Carboranes / [electronic resource] by Russell N. Grimes. 3rd ed. New York : Academic Press, [2016] �2016 1 online resource (xv, 1041 pages) : illustrations. text txt rdacontent computer c rdamedia online resource cr rdacarrier Organometallic chemistry Includes bibliographical references and index. Print version record. Carboranes, Third Edition, by Russell Grimes, is the definitive resource on the subject. Completely updated with a wealth of research and review articles published in this active field since the previous volume was released in 2011, the book provides a readable and concise introduction to the basic principles underlying the synthesis, structures, and reactions of carboranes, heterocarboranes, and metallacarboranes. Following the valuable foundational information, the book explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science. These disciplines include polymer science, catalysis, biomedicine, nanomaterials, and others. Front Cover; Carboranes; Copyright; Dedication; Contents; Preface to the Third Edition; Preface to the Second Edition; Chapter 1: Introduction and History; References; Chapter 2: Structure and Bonding; 2.1. General perspective; 2.2. Nomenclature and numbering; 2.3. The localized-bond approach; 2.4. Structural patterns in boron clusters; 2.5. Extensions of the electron-counting rules; 2.6. Electron-counting in classically bonded clusters; 2.7. Isomer stability and cage rearrangement; 2.8. Cluster aromaticity; 2.9. ``Electron Deficiency�� in Polyhedral Boron Clusters; References. Chapter 3: Synthesis and Reactivity: An Overview3.1. General preparative routes to carboranes; 3.1.1. Borane-Alkyne Gas Phase Reactions; 3.1.2. Borane-Alkyne Reactions in Solution; 3.1.3. Carborane-Alkyne Reactions; 3.1.4. Carbon Insertion Via Cyano- and Isocyanoboranes; 3.1.5. Carboranes from Organoboranes; 3.2. Interconversion reactions; 3.2.1. Polyhedral Rearrangement; 3.2.2. Metal-Promoted Cage Fusion; 3.2.3. Polyhedral Expansion and Contraction; 3.3. Substitution at cage carbon and boron atoms; 3.4. Carboranes as substituents and ligands. Chapter 4: Small Carboranes: Four- to Six-Vertex Clusters4.1. Overview; 4.2. 4-Vertex open clusters; 4.2.1. CB3Hx and C2B2Hx; 4.3. 5-Vertex open clusters; 4.3.1. Nido- and Arachno-CB4 Systems; 4.3.2. Nido-1,2-C2B3H7; 4.3.3. Other Open-Cage C2B3 Clusters; 4.3.4. Nido-C3B2 Clusters; 4.4. 5-Vertex closo clusters; 4.4.1. CB4Hx; 4.4.2. 1,5-C2B3H5; 4.4.2.1. Synthesis; 4.4.2.2. Structure and Bonding; 4.4.2.3. Physical Properties and Reactivity; 4.4.3. Closo-C3B2H5+; 4.5. 6-Vertex open clusters; 4.5.1. Nido-2-CB5H9; 4.5.1.1. Synthesis; 4.5.1.2. Structure and Properties; 4.5.2. Hypho-CB5H13. 4.5.3. Nido-2,3-C2B4H84.5.3.1. Synthesis; 4.5.3.2. Structure and Properties; 4.5.4. Nido-2,4-C2B4H8; 4.5.4.1. Synthesis; 4.5.4.2. Structure and Properties; 4.5.5. Arachno- and Hypho-C2B4Hx Clusters; 4.5.6. Nido-2,3,4-C3B3H7; 4.5.6.1. Synthesis; 4.5.6.2. Structure and Properties; 4.5.7. Nido-2,3,5-C3B3H7; 4.5.7.1. Synthesis; 4.5.7.2. Structure and Properties; 4.5.8. Nido-2,3,4,5-C4B2H6; 4.5.8.1. Synthesis; 4.5.8.2. Structure and Properties; 4.5.9. Nido-2,3,4,5,6-C5BH6+; 4.5.9.1. Synthesis; 4.5.9.2. Structure and Properties; 4.6. 6-Vertex closo clusters; 4.6.1. 1-CB5H7 and 1-CB5H6- 4.6.1.1. Synthesis4.6.1.2. Structure and Properties; 4.6.2. 1,2- and 1,6-C2B4H6; 4.6.2.1. Synthesis; 4.6.2.2. Structure and Physical Properties; 4.6.2.3. Reactions of Closo-1,2-C2B4 Clusters; 4.6.2.4. Reactions of Closo-1,6-C2B4 Clusters: Hydrolysis, Methanolysis, and Oxidation; 4.6.2.5. Polyhedral Expansion; 4.6.2.6. Cage Linkage; 4.6.2.7. Introduction of Substituents; References; Chapter 5: Intermediate Carboranes: Seven- to Nine-Vertex Clusters; 5.1. Overview; 5.2. 7-Vertex open clusters; 5.2.1. Nido-C2B5H8-; 5.3. 7-Vertex closo clusters; 5.3.1. 2-CB6H7-; 5.3.2. 2,3-C2B5H7. Carboranes. SCIENCE Chemistry Organic. bisacsh Carboranes. fast (OCoLC)fst00846954 Carborane gnd (DE-588)4147321-8 Carboranes. ram Carborane. swd Electronic books. Print version: Grimes, Russell N., 1935- Carboranes. New York, Academic Press, 2016 9780128018941 Organometallic chemistry. ScienceDirect http://www.sciencedirect.com/science/book/9780128018941 247399 247399