06056cam a2200577Ia 4500 ocn885009092 OCoLC 20190328114808.0 m o d cr ||||||||||| 140722s2015 ne a ob 001 0 eng d UKMGB eng pn UKMGB OCLCO N$T YDXCP OPELS OCLCF EBLCP DEBSZ OCLCQ U3W D6H CUY ZCU MERUC ICG DKC (S 016802671 Uk 897650677 902830696 9780080982243 (electronic bk.) 0080982247 (electronic bk.) 9780080982120 0080982123 (OCoLC)885009092 (OCoLC)897650677 (OCoLC)902830696 QD305.P46 SCI 013040 bisacsh 547.07 23 Timperley, Chris, author. Best synthetic methods : Organophosphorus (V) chemistry / [electronic resource] co-authored and edited by Chris Timperley. Amsterdam : Academic Press, �2015. 1 online resource : illustrations text txt rdacontent still image sti rdacontent computer c rdamedia online resource cr rdacarrier Best synthetic methods Includes bibliographical references and index. Online resource; title from PDF title page (EBSCO, viewed December 12, 2014). Best Synthetic Methods: ORGANOPHOSPHORUS (V) CHEMISTRY provides systematic coverage of the most common classes of pentavalent organophosphorus compounds and reagents (including phosphonyl, phosphoryl, and organophosphates), and allows researchers an easy point of entry into this complex and economically important field. The book follows the Best Synthetic Methods format, containing practical methods, synthetic tips, and shortcuts. Where relevant, articles include toxicity data and historical context for the reactions. Typical analytical and spectroscopic data are also presented to enable scientists to identify key compound characteristics. The book is a valuable companion to research chemists in both academia and industry, summarizing the best practical methods (often originating in difficult-to-access, foreign-language primary literature) in one place. It is ideally suited for those working on industrial applications of these compounds, including insecticides, herbicides, flame retardants, and plasticizers. Front Cover; Best Synthetic Methods; OTHER VOLUMES IN THE SERIES; Best Synthetic Methods; Copyright; ACKNOWLEDGEMENTS; REFERENCES; 1.4 PHOSPHORUS COMPOUNDS IN LIVING SYSTEMS; 1.5.3 ORGANOPHOSPHORUS PESTICIDES; 1.6 NOMENCLATURE OF ORGANOPHOSPHORUS COMPOUNDS; 1.7 CHIRAL PHOSPHORUS COMPOUNDS AND BIOLOGICAL IMPLICATIONS; 1.8 PHOSPHORUS-CONTAINING PHARMACEUTICALS; 1.9 FIRE RETARDANTS AND FIRE-EXTINGUISHING COMPOUNDS; 1.10 TOXICOLOGY AND MEDICAL TREATMENT OF ORGANOPHOSPHORUS COMPOUNDS; 1.11 FLUOROGENIC NERVE AGENT MIMICS FOR SCREENING FOR IMPROVED BIOSCAVENGERS. 880-01 2.23 s-alkyl alkylphosphonochloridothiolates r(r2)p(o)cl2.24 alkyl alkylphosphonofluoridates r(r2)p(o)f; 2.25 n-alkyl or n, n-dialkyl alkylphosphonamidofluoridates r(r2 n)p(o)f (x=h or r2 ; 2.26 s-alkyl alkylphosphonofluoridothiolates r(r2)p(o)f; 2.27 alkyl alkylphosphonocyanidates r(r2)p(o)cn; 2.28 alkyl alkylphosphonic acids r(r2)p(o)oh; 2.29 alkylphosphonofluoridic anhydrides r(f)p(o)op(o)(f)r; 2.30 dialkyl dialkylpyrophosphonates r(r2)p(o)op(o)(or2 r; 2.31 n, n-dialkyl-p-alkylphosphonamidic anhydrides r(r2 n)p(o)op(o)(nr2)r. 2.32 s, s2 dialkyl dialkyldithiopyrophosphonates r(r2)p(o)op(o)(sr2 r2.33 o-alkyl n-alkyl alkylphosphonamidates rp(o)(nr2)or; 2.34 bis(n, n-dialkyl) alkylphosphonodiamidates rp(o)(nr2)2; 2.35 o, s-dialkyl alkylphosphonothiolates rp(o)(or)sr; 2.36 s-alkyl n-alkyl (or n, n-dialkyl) alkylphosphonamidothiolates rp(o)(nr2)sr; 2.37 s, s2 dialkyl alkylphosphonodithiolates rp(o)(sr2)2; references; 3.9 s-alkyl alkylphosphonochloridothiolothionates rs(r2 p(s)cl; 3.13 alkyl alkyl/aryl alkylphosphonothionates ro(r2 p(s)or2 ; 4.9 alkyl phosphorodiisothiocyanatidates rop(o)(ncs)2. 4.35 trialkyl phosphates (ro)2p(o)or4.39 dialkyl enolphosphates (ro)2p(o)ocrcr2 (perkow reaction); 4.40 dialkyl phosphorazidates (ro)2p(o)n3; 4.41 dialkyl phosphoramidates (ro)2p(o)nr2 (todd-atherton reaction); 4.42 dialkyl n-arylphosphoramidates (ro)2p(o)nhar; 4.43 diaryl phosphoramidates (aro)2p(o)nr2; 4.44 dialkyl n-methyl-n-(phosphoryl)phosphoramidates (ro)2p(o)n(me)p(x)r2; 4.45 dialkyl n-methyl-n-acylphosphoramidates (ro)2p(o)n(me)cor2 4.46 disubstituted n-aryl(or alkyl)-n-chlorophosphoramidates (ro)2p(o)n(cl)ar; 4.47 dialkyl n, n-dihalophosphoramidates (ro)2p(o)nx2 (x=cl or br). Organophosphorus compounds. Organophosphorus compounds Synthesis. SCIENCE Chemistry Organic. bisacsh Organophosphorus compounds. fast (OCoLC)fst01047997 Organophosphorus compounds Synthesis. fast (OCoLC)fst01048004 Electronic books. Electronic books. lcgft Print version: Timperley, Chris. Best Synthetic Methods: ORGANOPHOSPHORUS (V) CHEMISTRY. Burlington : Elsevier Science, �2014 9780080982120 Best synthetic methods. ScienceDirect http://www.sciencedirect.com/science/book/9780080982120 505-01/(S 1.13 WORKING SAFELY WITH ORGANOPHOSPHORUS COMPOUNDSREFERENCES; 2.5 ALKYLPHOSPHONIC DIFLUORIDES RP(O)F2; 2.9 ALKYLPHOSPHONIC ISOTHIOCYANATOFLUORIDES RP(O)(NCS)F; 2.16 DIALKYL (Sa(B-HYDROXYPHOSPHONATES (RO)2P(O)CH(OH)R2 (PUDOVIK REACTION); 2.17 DIALKYL (Sa(B-SILOXYPHOSPHONATES (RO)2P(O)CH(OSIME3)R2 (ABRAMOV REACTION); 2.18 DIALKYL (Sa(B-AMINOPHOSPHONATES (RO)2P(O)CR2NR2 (KABACHNIK-FIELDS REACTION); 2.19 DIALKYL ALKENYLPHOSPHONATES (RO)2P(O)CCR2; 2.20 DIALKYL ALKYNYLPHOSPHONATES (RO)2P(O)CaCR; 2.22 N, N-DIALKYL ALKYLPHOSPHONAMIDOCHLORIDATES R(R22N)P(O)CL. 246945 246945