04443cam a2200481Mi 4500 ocn913618259 OCoLC 20190328114808.0 m o d cr cn||||||||| 140719s2014 vtu o 000 0 eng d UAB eng pn UAB OCLCO EBLCP OPELS N$T NOC YDXCP OCLCF DEBSZ UIU OCLCQ ESU OCLCQ U3W D6H YOU DEBBG (S 884014639 9780124171916 (electronic bk.) 0124171915 (electronic bk.) 9780124171855 (OCoLC)913618259 (OCoLC)884014639 QD262 SCI 013040 bisacsh 547.2 Strategies and tactics in organic synthesis : Vol. 10 / [electronic resource] edited by Michael Harmata. Burlington : Elsevier Science, 2014. 1 online resource. text txt rdacontent computer c rdamedia online resource cr rdacarrier Strategies and Tactics in Organic Synthesis ; v. 10 Print version record. Substrate-Directed Heck-Matsuda Arylations; ( -- )-Berkelic Acid: Lessons Learned From Our Investigations on a Scalable Total Synthesis; The Mysterious Case of the Kingianins; Total Synthesis of Chinensiolide B: An Exercise in Functional Group Selectivity with the Help of a Fortuitous Side Product and a Good Nose; Syntheses of the Bisindole Alkaloids of the Genera Borreria and Flindersia; Synthesis of (�)-Amathaspiramide F: Stereochemical Switch of a [2,3]-Stevens ; Oxabicyclic Building Blocks as Key Intermediates in the Synthesis of the Natural Products ( -- )-Platensimycin and (+)-Frondosin A; Structure Inspires a New Method That Delivers the Synthesis of Natural Products and Analogs in the Pederin Family; Gliocladin C: The Development and Application of a Pyrroloindoline-Indole Radical Coupling Reaction; Studies in the Synthesis of Biaryl Natural Products: The 6,6'-Binaphthopyranones; Sleepless Nights: The Total Synthesis of the Anticancer Australian Rainforest Polyketide EBC-23; Total Synthesis of the Crinipellins. A classic in the area of organic synthesis, Strategies and Tactics in Organic Synthesis provides a forum for investigators to discuss their approach to the science and art of organic synthesis. Rather than a simple presentation of data or a secondhand analysis, we are given stories that vividly demonstrate the power of the human endeavor known as organic synthesis and the creativity and tenacity of its practitioners. Organic compounds Synthesis. SCIENCE Chemistry Organic. bisacsh Organic compounds Synthesis. fast (OCoLC)fst01047668 Electronic books. Harmata, Michael. Print version: Harmata, Michael. Strategies and Tactics in Organic Synthesis. Burlington : Elsevier Science, �2014 9780124171855 Strategies and Tactics in Organic Synthesis ; v. 10. ScienceDirect http://www.sciencedirect.com/science/book/9780124171855 ScienceDirect http://www.sciencedirect.com/science/bookseries/18746004/10 505-00 7. Synthesis of Kingianin A8. ``Go Fish� � -Pursuit of the Intermolecular RCDA Approach; 9. Formal Synthesis of Kingianin A and Synthesis of Kingianins D, F, H, and J; 10. NCI 60 Test Results for Kingianins A (NSC#D-768505/1) and H (NSC#D-768506/1); 11. Reconsidering the Biosynthesis; 12. Conclusions; Acknowledgments; References; Chapter 4: Total Synthesis of Chinensiolide B: An Exercise in Functional Group Selectivity with the Help of a Fortuitous Side product and a good nose; 1. Introduction; 1.1. Chinensiolide and Other (Sa(B-Methylene (Sd(B-Lactones in Nature 505-00 1.2. Traditional Methods for the Synthesis of (Sa(B-Methylene (Sd(B-Lactones1.3. Use of 2-Alkoxycarbonyl Allylboronates to Access (Sa(B-Methylene (Sd(B-Lactones; 2. Model Studies and Retrosynthetic Analysis; 2.1. Retrosynthetic Analysis; 2.2. Model Studies; 3. Design and Synthesis of the Key Allylboronate; 3.1. Selection of the Protecting Group; 3.2. Synthesis of Disubstituted Allylboronate 7; 4. Synthesis of the Cyclopentyl Aldehyde Substrate; 4.1. Literature Precedent; 4.2. Preparation of Aldehyde 6; 5. Critical Moment-The Key Aldehyde Allylboration Step 246933 246933