05933cam a2200757 i 4500 ocn881518526 OCoLC 20171029122407.0 m o d cr ||||||||||| 140618s2014 nju ob 001 0 eng 2014024096 9781118788998 (epub) 1118788990 (epub) 9781118789032 (pdf) 1118789032 (pdf) 9781118788981 1118788982 1118452232 (hardback) 9781118452233 (hardback) 9781322214696 (MyiLibrary) 1322214697 (MyiLibrary) 9781118452233 (hardback) CHBIS 010442269 CHVBK 334092930 DEBSZ 431801061 NZ1 15913262 DEBBG BV043396927 (OCoLC)881518526 (OCoLC)951971601 DLC eng rda pn DLC N$T YDXCP EBLCP IDEBK DG1 VRC OCLCF CDX COO RECBK DEBSZ OCLCQ DEBBG pcc MAIN QD505 SCI 013050 bisacsh 541/.395 23 SCI013040 SCI013050 SCI013000 bisacsh Homogeneous catalysis for unreactive bond activation / edited by Dr. Zhang-Jie Shi, professor of chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing, China. [electronic resource] Hoboken, New Jersey : Wiley, 2014. 1 online resource. text txt rdacontent computer c rdamedia online resource cr rdacarrier Machine generated contents note: Preface Contributor List Chapter 1: Catalysis in C-Cl Activation Zhong-Xia Wang and Wang-Jun Guo Chapter 2: Homogeneous Transition-metal Catalyzed C-F Activation Shang-Dong Yang Chapter 3: Homogeneous Transition-metal Catalzyed C-N Activation Xiao-Bing Wan Chapter 4: Catalytic Carbon-Sulfur Bond Activation and Transformations Zhengkun Yu Chapter 5: Homogeneous Transition-Metal-Catalzyed C-O Bond Activation Da-Gang Yu, Shuang Luo, Fei Zhao, and Zhang-Jie Shi Chapter 6: Homogeneous Transition-Metal-Catalyzed C-H Bond Functionalization Bi-Jie Li and Zhang-Jie Shi Chapter 7: Catalysis in C-C Activation Hu Li and Zhang-Jie Shi. Includes bibliographical references and index. Title Page; Copyright; Preface; Contributors; Chapter 1: Catalysis In C-Cl Activation; 1.1 Introduction; 1.2 Reductive Dechlorination; 1.3 Formation of C-C Bonds; 1.4 Formation of C-N Bonds; 1.5 Formation of C-O Bonds; 1.6 Formation of C-S Bonds; 1.7 Formation of C-B Bonds; 1.8 Conclusion and Outlook; References; Chapter 2: Homogeneous Transition-Metal-Catalyzed C-F Activation; 2.1 Background; 2.2 Transition-Metal-Mediated Cross-Coupling Reactions byC-F Bond Activation; 2.4 Transition-Metal-Promoted Dehydrofluorination by C-F Bond Activation 2.5 The Applications of C-F Activation in Organic Synthesis2.6 Summary and Outlook; References; Chapter 3: Homogeneous Transition-Metal Catalyzed C-N Activation; 3.1 Background; 3.2 Palladium-Catalyzed C-N Activation; 3.3 Ruthenium-Catalyzed C-N Activation; 3.4 Nickel-Catalyzed C-N Activation; 3.5 Copper-Catalyzed C-N Activation; 3.6 Iron-Catalyzed C-N Activation; 3.7 Other-Transition-Metal-Catalyzed C-N Activation; 3.8 Computationally and Experimentally Mechanistic Studies; 3.9 Summary and Outlook; References; Chapter 4: Catalytic Carbon-Sulfur Bond Activation and Transformations 4.1 Background4.2 C-S Bond Activation by Transition Metal Compounds; 4.3 Catalytic C-S Cleavage in Thioesters; 4.4 Catalytic C-S Cleavage in Dithioacetals; 4.5 Diverse Catalytic C-S Cleavage; 4.6 Summary and Outlook; References; Chapter 5: Homogeneous Transition-Metal-Catalyzed C-O Bond Activation; 5.1 Introduction; 5.2 Palladium-Catalyzed C-O Bond Activation; 5.3 Nickel-Catalyzed C-O Bond Activation; 5.4 Other-Transition-Metal-Catalyzed C-O Bond Activation; 5.5 Summary and Outlook; References; Chapter 6: Homogeneous Transition-Metal-Catalyzed C-H Bond Functionalization; 6.1 Overview 6.2 Mechanism of C-H Cleavage6.3 Directed C-H Oxidation; 6.4 Hydroarylation; 6.5 Direct Arylation; 6.6 Carbonylation; 6.7 Hydroacylation; 6.8 Alkane Dehydrogenation; 6.9 Borylation and Silylation; 6.10 Summary and Outlook; References; Chapter 7: Catalysis in C-C Activation; 7.1 Introduction: Importance and Challenges in C-C Activation; 7.2 C-C Activation of Strained Molecules; 7.3 C-C Activation of Unstrained Molecules; 7.4 Summary and Perspective; References; Index; End User License Agreement "This book offers a comprehensive overview of different catalytic reactions applied to the activation of chemical bonds. Each of the seven chapters cover key C-X classes where carbon is combined with another element: chlorine, fluorine, nitrogen, sulfur, oxygen, hydrogen, and carbon"-- Provided by publisher. Print version record and CIP data provided by publisher. Homogeneous catalysis. Carbon, Activated. Chemical bonds. SCIENCE Chemistry Organic. bisacsh SCIENCE Chemistry Physical & Theoretical. bisacsh SCIENCE Chemistry General. bisacsh Carbon, Activated. fast (OCoLC)fst00846894 Chemical bonds. fast (OCoLC)fst00852856 Homogeneous catalysis. fast (OCoLC)fst01909666 Electronic books. Electronic books. Shi, Zhangjie, 1974- editor. Print version: Homogeneous catalysis for unreactive bond activation. Hoboken, New Jersey : Wiley, 2014 9781118452233 (DLC) 2014008375 http://onlinelibrary.wiley.com/book/10.1002/9781118788981 Wiley Online Library ddc BK 207542 207542