06082cam a2200793 i 4500 ocn862222401 OCoLC 20171105094535.0 m o d cr ||||||||||| 131105s2014 nju ob 001 0 eng 2013044444 9781118711569 (epub) 1118711564 (epub) 9781118711705 (pdf) 111871170X (pdf) 9781118711620 (mobi) 1118711629 (mobi) 9781118207949 (cloth) 9781118711613 1118711610 1118207947 9781118207949 9781306638869 1306638860 CHBIS 010056068 CHVBK 316973637 NZ1 15626491 CHVBK 325944172 CHBIS 010259676 NZ1 15922667 DEBSZ 431671184 DEBBG BV041997401 (OCoLC)862222401 (OCoLC)908035553 (OCoLC)960200400 (OCoLC)961663674 (OCoLC)962723462 DLC eng rda DLC YDX EBLCP N$T IDEBK MHW YDXCP E7B DG1 RECBK CUI CDX OCLCF COO B24X7 OCLCO DEBSZ LOA DG1 pcc MAIN QD505 SCI 013040 bisacsh 547/.215 23 Olefin metathesis : theory and practice / edited by Dr. Karol Grela, Institute of Organic Chemistry, Kasprzaka, Poland. [electronic resource] Hoboken, New Jersey : Wiley, [2014] 1 online resource. text rdacontent computer rdamedia online resource rdacarrier "Zespol III." Includes bibliographical references and index. Title Page; Copyright; Preface; Reference; Contributors; Part I: Applications of Olefin Metathesis Reactions; Section 1: Introduction; Chapter 1: Olefin Metathesis Reactions: From A Historical Account to Recent Trends; 1.1 Introduction; 1.2 The Metathesis Reactions: Exchanges of Carbenes and Carbynes; 1.3 The Early Days of Olefin Metathesis in American Industry; 1.4 Unsuccessful Attempts to Solve the Mechanistic Puzzle; 1.5 The Chauvin Mechanism: A Metathesis Dance; 1.6 The Importance of the Chauvin Mechanism for Overall Organometallic Catalysis 1.7 Schrock's High Oxidation State Alkylidene and Alkylidyne Complexes1.8 Grubbs' Approach and the Ru Olefin Metathesis Catalysts; 1.9 Olefin Metathesis in Aqueous Solvents and Water; 1.10 Olefin Metathesis in Other "Green Solvents": Ionic Liquids and CO2; 1.11 Solid Catalyst Supports; 1.12 Metal Contamination of the Metathesis Reaction Products; 1.13 Industrial Applications; 1.14 Applications to Organic Synthesis; 1.15 Alkyne Metathesis; 1.16 Alkane Metathesis; 1.17 Polymerization Metathesis and Polymer Materials; 1.18 Concluding Remarks; Acknowledgments; References Section 2: Types of Olefin Metathesis ReactionsChapter 2: Cross Metathesis; 2.1 Introduction; 2.2 Functional Group Influence on the Metathesis Outcome; 2.3 E/Z Selectivity Control; 2.4 Outlook and Perspectives; Acknowledgments; References; Chapter 3: Ring-Closing Metathesis; 3.1 Introduction; 3.2 General Factors in Cyclization Efficiency; 3.3 Scope, Challenges, and Opportunities; 3.4 Practical Aspects; 3.5 Practical Examples; 3.6 Industrial Applications of RCM; 3.7 Conclusions; Acknowledgments; References; Chapter 4: Ene-Yne Metathesis; 4.1 Introduction 4.2 Ene-Yne Metathesis not Involving Cascades4.3 Tandem Processes Involving En(e)Yne Metathesis; 4.4 Conclusion and Outlook; References; Chapter 5: Domino and other Olefin Metathesis Reaction Sequences; 5.1 Introduction; 5.2 Domino Reactions; 5.3 Metathesis/Non-Metathesis Reaction Sequences; References; Chapter 6: Enantioselective Olefin Metathesis; 6.1 General Introduction; 6.2 Asymmetric Ring-Closing Metathesis (ARCM); 6.3 Tandem Asymmetric Ring-Opening/Cross Metathesis (AROM/CM) or Tandem Asymmetric Ring-Opening/Cross-Closing Metathesis (AROM/RCM); 6.4 Conclusion; References Chapter 7: Olefin Metathesis Polymerization7.1 Introduction; 7.2 ROMP-The Mechanism; 7.3 The Initiators/Catalysts; 7.4 ROMP-The Monomers; 7.5 ROMP-Applications; 7.6 Acyclic Diene Metathesis; 7.7 Cyclopolymerizations; 7.8 Conclusions; References; Section 3: Applications of Olefin Metathesis Reactions; Chapter 8: Applications in the Synthesis of Natural and Biologically Active Molecules; 8.1 Introduction; 8.2 Ring-Closing Metathesis (RCM); 8.3 Relay Ring-Closing Metathesis (RRCM); 8.4 Temporary Tether and RCM (TT-RCM); 8.5 Cross-Metathesis (CM); 8.6 Ring-Opening Metathesis (ROM) This is a complete examination of the theory and methods of modern olefin metathesis, one of the most widely used chemical reactions in research and industry. Provides basic information for non-specialists, while also explaining the latest trends and advancements in the field to experts. Discusses the various types of metathesis reactions, including CM, RCM, enyne metathesis, ROMP, and tandem processes, as well as their common applications. Outlines the tools of the trade-from the important classes of active metal complexes to optimal reaction conditions. Description based on print version record and CIP data provided by publisher. Metathesis (Chemistry) Catalysis. Alkenes. SCIENCE Chemistry Organic. bisacsh Alkenes. fast (OCoLC)fst00805415 Catalysis. fast (OCoLC)fst00848867 Metathesis (Chemistry) fast (OCoLC)fst01018340 Electronic books. Electronic books. Grela, Karol, 1970- editor of compilation. Print version: Olefin metathesis Hoboken, New Jersey : John Wiley & Sons, [2014] 9781118207949 (DLC) 2013041990 http://onlinelibrary.wiley.com/book/10.1002/9781118711613 Wiley Online Library ddc BK 207077 207077