06505cam a2200757 i 4500 ocn830124718 OCoLC 20171107092632.0 m o d cr ||||||||||| 130314s2013 nju ob 001 0 eng 2013010397 9781118629994 (epub) 111862999X (epub) 9781118630167 (pdf) 1118630165 (pdf) 9781118630181 ( mobi) 1118630181 ( mobi) 9781118148921 (hardback) 9781118629871 1118629876 9781299731738 (MyiLibrary) 1299731732 (MyiLibrary) 1118148924 (hbk.) EB00067048 Recorded Books AU@ 000050651150 NZ1 15340529 DKDLA 820120-katalog:000664706 DEBSZ 431454000 (OCoLC)830124718 (OCoLC)857437591 (OCoLC)865013011 (OCoLC)961635305 (OCoLC)962648127 504424 MIL DLC eng rda DLC YDX EBLCP N$T IDEBK DG1 CUS NOC E7B YDXCP COO CDX OCLCF IUL RECBK DEBSZ pcc MAIN QD331 SCI 013040 bisacsh 547/.6 23 SCI013040 bisacsh Transition-metal-mediated aromatic ring construction / edited by Ken Tanaka, Tokyo University of Agriculture and Technology, Tokyo, Japan. [electronic resource] Hoboken, New Jersey : Wiley, [2013] 1 online resource. text rdacontent computer rdamedia online resource rdacarrier Includes bibliographical references and index. Title Page; Copyright; Contributors; Preface; Part I: [2 + 2 + 2] and Related Cycloaddition Reactions; Chapter 1: Cobalt-Mediated [2 + 2 + 2] Cycloaddition; 1.1 INTRODUCTION; 1.2 SYNTHESIS OF BENZENES; 1.3 SYNTHESIS OF HETEROCYCLES; 1.4 MECHANISTIC ASPECTS; 1.5 SYNTHETIC APPLICATIONS; 1.6 SUMMARY AND OUTLOOK; REFERENCES; Chapter 2: Nickel-Mediated [2 + 2 + 2] Cycloaddition; 2.1 INTRODUCTION; 2.2 SYNTHESIS OF BENZENES; 2.3 CYCLOADDITION OF ALKYNES AND NITRILES; 2.4 CYCLOADDITION OF ALKYNES AND IMINES; 2.5 CYCLOADDITION OF ALKYNES AND CARBON DIOXIDE; 2.6 CYCLOADDITION OF ALKYNES AND ISOCYANATES 2.7 CYCLOADDITION OF ALKYNES AND CARBODIIMIDE2.8 CYCLOADDITION OF DIYNES AND KETENES; 2.9 CYCLOADDITION OF ARYNES; 2.10 MECHANISM; 2.11 SUMMARY AND OUTLOOK; REFERENCES; Chapter 3: Ruthenium-Mediated [2 + 2 + 2] Cycloaddition; 3.1 INTRODUCTION; 3.2 SYNTHESIS OF BENZENES; 3.3 SYNTHESIS OF HETEROCYCLES; 3.4 MECHANISM OF RUTHENIUM-CATALYZED [2 + 2 + 2] CYCLOADDITIONS; 3.5 SYNTHETIC APPLICATIONS; 3.6 SUMMARY AND OUTLOOK; REFERENCES; Chapter 4: Rhodium-Mediated [2 + 2 + 2] Cycloaddition; 4.1 INTRODUCTION; 4.2 SYNTHESIS OF BENZENES; 4.3 SYNTHESIS OF PYRIDINES 4.4 SYNTHESIS OF PYRIDONES AND RELATED HETEROCYCLES4.5 SUMMARY AND OUTLOOK; REFERENCES; Chapter 5: Iridium-Mediated [2 + 2 + 2] Cycloaddition; 5.1 INTRODUCTION; 5.2 SYNTHESIS OF BENZENE DERIVATIVES; 5.3 SYNTHESIS OF HETEROCYCLIC COMPOUNDS; 5.4 MECHANISTIC ASPECTS; 5.5 SUMMARY AND OUTLOOK; REFERENCES; Chapter 6: [2 + 2 + 2] and Related Cycloadditions Mediated by Other Transition Metals; 6.1 INTRODUCTION; 6.2 PALLADIUM-CATALYZED [2 + 2 + 2] AND [2 + 2 + 1] CYCLOADDITIONS; 6.3 IRON-CATALYZED [2 + 2 + 2] CYCLOADDITION; 6.4 MANGANESE-CATALYZED [2 + 2 + 2] CYCLOADDITION 6.5 RHENIUM-CATALYZED [2 + 2 + 2], [2 + 1 + 2 + 1], AND [2 + 2 + 1 + 1] CYCLOADDITIONS6.6 OTHER TRANSITION-METAL-CATALYZED [2 + 2 + 2] CYCLOADDITION; 6.7 SUMMARY AND OUTLOOK; REFERENCES; Chapter 7: Application to the Synthesis of Natural Products; 7.1 INTRODUCTION; 7.2 CONSTRUCTION OF BENZENE RINGS; 7.3 CONSTRUCTION OF A HETEROCYCLIC RING; 7.4 MISCELLANEOUS; 7.5 SUMMARY AND OUTLOOK; REFERENCES; Chapter 8: Synthesis of Planar Chiral Aromatic Compounds via [2 + 2 + 2] Cycloaddition; 8.1 INTRODUCTION; 8.2 COBALT-CATALYZED [2 + 2 + 2] CYCLOADDITION; 8.3 RHODIUM-CATALYZED [2 + 2 + 2] CYCLOADDITION 8.4 ENANTIOSELECTIVE [2 + 2 + 2] CYCLOADDITION8.5 SUMMARY AND OUTLOOK; REFERENCES; Chapter 9: Synthesis of Axially Chiral Aromatic Compounds via [2 + 2 + 2] Cycloaddition; 9.1 INTRODUCTION; 9.2 COBALT-CATALYZED ENANTIOSELECTIVE [2 + 2 + 2] CYCLOADDITION; 9.3 IRIDIUM-CATALYZED ENANTIOSELECTIVE [2 + 2 + 2] CYCLOADDITION; 9.4 RHODIUM-CATALYZED ENANTIOSELECTIVE [2 + 2 + 2] CYCLOADDITION; 9.5 ENANTIOSELECTIVE SYNTHESIS OF AXIALLY CHIRAL ANILIDES AND BEZAMIDES; 9.6 SUMMARY AND OUTLOOK; REFERENCES; Chapter 10: Synthesis of Helically Chiral Aromatic Compounds via [2 + 2 + 2] Cycloaddition "Recent significant advances with transition-metal-mediated reactions have opened promising new routes to complex aromatic compounds and have been the subject of intense research in recent years. Featuring practical and efficient reactions to help organic chemists synthesize an important class of compounds, Transition-Metal-Mediated Aromatic Ring Construction provides a valuable guide to methods, synthetic routes, and strategies to construct aromatic rings. Chapters devoted to efficient and practical reactions demonstrate how to use them for the synthesis of various complex aromatic compounds"-- Provided by publisher. "This book covers transition-metal-mediated reactions with applications for constructing aromatic rings, which are an important class of industrial chemical compounds"-- Provided by publisher. Description based on print version record and CIP data provided by publisher. Aromatic compounds Synthesis. Transition metal catalysts. SCIENCE / Chemistry / Organic. bisacsh Aromatic compounds Synthesis. fast (OCoLC)fst00815028 Transition metal catalysts. fast (OCoLC)fst01154758 Electronic books. Electronic books. Electronic books. local Tanaka, Ken, 1967- Print version: Transition-metal-mediated aromatic ring construction Hoboken, New Jersey : Wiley, [2013] 9781118148921 (DLC) 2012049882 http://onlinelibrary.wiley.com/book/10.1002/9781118629871 Wiley Online Library ddc BK 206575 206575