08081cam a2200853 i 4500 ocn828334158 OCoLC 20171107094948.0 m o d cr ||||||||||| 130222s2013 nju ob 001 0 eng 2013007823 9781118356753 (epub) 1118356756 (epub) 9781118356746 (pdf) 1118356748 (pdf) 9781118356739 (mobi) 111835673X (mobi) 9781118356760 (electronic bk.) 1118356764 (electronic bk.) 9781299534063 (MyiLibrary) 1299534066 (MyiLibrary) 9780470915523 (cloth) 0470915528 (cloth) EB00063427 Recorded Books AU@ 000053305875 CHBIS 010026879 CHDSB 006130003 CHVBK 124146767 CHVBK 306244772 DEBBG BV041912846 DEBSZ 431393842 DKDLA 820120-katalog:000664169 NZ1 15340370 DEBBG BV043395486 (OCoLC)828334158 (OCoLC)843637040 (OCoLC)850147373 (OCoLC)864911064 (OCoLC)961598699 (OCoLC)962702794 DLC eng rda pn DLC YDX N$T DG1 IDEBK CUS E7B YDXCP UBY CDX COO NOC RECBK EBLCP DEBSZ MHW CHVBK DEBBG OCLCQ pcc MAIN QD281.O9 SCI 013050 bisacsh 541/.393 23 Liquid phase oxidation via heterogeneous catalysis : organic synthesis and industrial applications / edited by Mario G. Clerici, formerly with Enitecnologie (ENI Group) ; San Donato Milano, Italy, Oxana A. Kholdeeva, Boreskov Institute of Catalysis, Novosibirsk, Russia. [electronic resource] Hoboken, New Jersey : Wiley, [2013] 1 online resource. text txt rdacontent computer c rdamedia online resource cr rdacarrier Includes index. Includes bibliographical references and index. Liquid Phase Oxidation via Heterogeneous Catalysis: Organic Synthesis And Industrial Applications; Contents; Preface; Contributors; Abbreviations; 1 Environmentally Benign Oxidants; 1.1 Introduction; 1.2 Oxygen (Air); 1.3 Alkylhydroperoxides; 1.4 Hydrogen Peroxide; 1.5 Conclusions; References; 2 Oxidation Reactions Catalyzed by Transition-Metal-Substituted Zeolites; 2.1 Introduction; 2.2 Synthesis and Characterization of Zeolites; 2.2.1 Isomorphous Metal Substitution; 2.2.2 Synthesis of Titanium Silicalite-1 (TS-1); 2.2.3 Characterization of Titanium Silicalite-1 (TS-1). 2.2.4 Ti-Beta, Synthesis and Characterization2.2.5 Other Ti Zeolites; 2.2.6 Other Metal Zeolites; 2.3 Catalytic Properties; 2.3.1 Hydroxylation of Alkanes; 2.3.2 Hydroxylation of Aromatic Compounds; 2.3.3 Oxidation of Olefinic Compounds; 2.3.4 Oxidation of Alcohol and Ether Compounds; 2.3.5 Reactions of Carbonyl Compounds; 2.3.6 Oxidation of N-Compounds; 2.3.7 Oxidation of S-Compounds; 2.4 Mechanistic Aspects; 2.4.1 The Nature of Active Species; 2.4.2 Hydroxylation; 2.4.3 Epoxidation; 2.4.4 Oxidation of Alcohols; 2.4.5 Ammoximation; 2.4.6 Decomposition of Hydrogen Peroxide. 2.4.7 Active Species, Adsorption and Catalytic Activity2.5 Stability of Metal-Substituted Zeolites to Reaction Conditions; 2.6 Conclusions; References; 3 Selective Catalytic Oxidation over Ordered Nanoporous Metallo-Aluminophosphates; 3.1 Introduction; 3.2 Synthesis; 3.2.1 Microporous Aluminophosphates; 3.2.2 Mesoporous Aluminophosphates; 3.3 Characterization; 3.4 Catalytic Properties; 3.4.1 Oxidation of Hydrocarbons; 3.4.2 Oxidation of Olefins; 3.4.3 Oxidation of Alcohols; 3.4.4 Oxidation of Phenols; 3.4.5 Ammoximation and Ammoxidation; 3.4.6 Baeyer-Villiger Oxidation. 3.4.7 Oxidation of Heterocycles3.5 Mechanistic Aspects; 3.6 Catalysts Stability; 3.7 Conclusion; References; 4 Selective Oxidations Catalyzed by Mesoporous Metal Silicates; 4.1 Introduction; 4.2 Synthesis and Characterization; 4.2.1 General Synthetic Approaches; 4.2.2 Characterization Techniques; 4.2.3 Sol-Gel Synthesis of Amorphous Mixed Oxides; 4.2.4 Thermolytic Molecular Precursor Method; 4.2.5 Templated Synthesis of Ordered Metal Silicates; 4.2.6 Postsynthesis Modifications; 4.2.7 Organic-Inorganic Hybrid Materials; 4.3 Catalytic Properties; 4.3.1 Oxidation of Alkanes. 4.3.2 Oxidation of Aromatic Compounds4.3.3 Oxidation of Olefins; 4.3.4 Oxidation of Alcohols; 4.3.5 Oxidation of Ketones and Aldehydes; 4.3.6 Oxidation of S-compounds; 4.3.7 Oxidation of Amines; 4.4 Mechanistic Aspects; 4.5 Stability; 4.5.1 Mechanisms of Deactivation; 4.5.2 Solving Problem of Hydrothermal Stability; 4.5.3 Hydrothermally Stable Catalysts: Scope and Limitations; 4.6 Conclusions and Outlook; References; 5 Liquid Phase Oxidation of Organic Compounds by Supported Metal-Based Catalysts with a Focus on Gold; 5.1 Introduction; 5.2 Catalyst Preparation and Characterization. BSets the stage for environmentally friendly industrial organic syntheses/b/ From basic principles to new and emerging industrial applications, this book offers comprehensive coverage of heterogeneous liquid, phase selective oxidation catalysis. It fully examines the synthesis, characterization, and application of catalytic materials for environmentally friendly organic syntheses. Readers will find coverage of all the important classes of catalysts, with an emphasis on their stability and reusability. iLiquid Phase Oxidation via Heterogeneous Catalysis/i features contributions from an international team of leading chemists representing both industry and academia. The book begins with a chapter on environmentally benign oxidants and then covers:ulliSelective oxidations catalyzed by TS,1 and other metal, substituted zeolites/liliSelective catalytic oxidation over ordered nanoporous metallo, aluminophosphates/liliSelective oxidations catalyzed by mesoporous metal, silicates/liliLiquid phase oxidation of organic compounds by supported metal, based catalysts/liliSelective liquid phase oxidations in the presence of supported polyoxometalates/liliSelective oxidations catalyzed by supported metal complexes/liliLiquid phase oxidation of organic compounds by metal, organic frameworks/liliHeterogeneous photocatalysis for selective oxidations with molecular oxygen/li/ul All the chapters dedicated to specific types of catalysts follow a similar organization and structure, making it easy to compare the advantages and disadvantages of different catalysts. The final chapter examines the latest industrial applications, such as the production of catechol and hydroquinone, cyclohexanone oxime, and propylene oxide. With its unique focus on liquid phase heterogeneous oxidation catalysis, this book enables researchers in organic synthesis and oxidation catalysis to explore and develop promising new catalytic materials and synthetic routes for a broad range of industrial applications. Print version record and CIP data provided by publisher. Oxidation. Oxidation Industrial applications. Heterogeneous catalysis. Heterogeneous catalysis Industrial applications. Heterogeneous catalysis. Heterogeneous catalysis Industrial applications. Oxidation. Oxidation Industrial applications. SCIENCE Chemistry Physical & Theoretical. bisacsh Electronic books. Electronic books. local Clerici, Mario G. Kholdeeva, Oxana A. Print version: Liquid phase oxidation via heterogeneous catalysis. Hoboken, New Jersey : Wiley, [2013] 9780470915523 (DLC) 2012047247 http://onlinelibrary.wiley.com/book/10.1002/9781118356760 Wiley Online Library ddc BK 206480 206480