Mason, Robert P. (Robert Peter) 1956- creator text bibliography Electronic books. Electronic books. nju 2013 monographic eng

electronic resource

1 online resource. "The textbooks that currently exist do not deal with this particular subject in a comprehensive fashion, and therefore this book is being proposed to full this gap"-- Cover; Title page; Copyright page; Contents; Preface; About the companion website; CHAPTER 1: Introduction; 1.1 A historical background to metal aquatic chemistry; 1.2 Historical problems with metal measurements in environmental media; 1.3 Recent advances in aquatic metal analysis; References; Problems; CHAPTER 2: An introduction to the cycling of metals in the biosphere; 2.1 The hydrologic cycle; 2.2 An introduction to the global cycling of trace metal(loid)s; 2.2.1 The sources and cycling of metal(loid)s in the biosphere; 2.2.2 Metal(loid) partitioning and solubility in natural waters. 2.2.3 Human influence over metal(loid) fate and transport2.2.4 Trace metal(loid) inputs to the atmosphere; 2.2.5 Metal(loid)s in the terrestrial environment and freshwater ecosystems; 2.2.6 The transport of metal(loid)s to the ocean; 2.2.7 Trace metal(loid)s in ocean waters; 2.2.8 Trace metal(loid) inputs from hydrothermal vents; 2.3 Global cycles of some important trace metals; 2.3.1 The global cycles of cadmium, copper, and zinc; 2.3.2 The global cycle of mercury and lead; 2.4 Chapter summary; References; Problems. CHAPTER 3: Chemical thermodynamics and metal(loid) complexation in natural waters3.1 Thermodynamic background for understanding trace metal(loid) complexation; 3.1.1 The relationship between free energy and the equilibrium constant; 3.1.2 Ionic strength effects; 3.1.3 Thermodynamic equilibrium, kinetics and steady state; 3.2 Bonding, electronic configuration, and complex formation; 3.2.1 Ligand Field Theory; 3.2.2 Thermodynamic effects of orbital splitting; 3.2.3 Inorganic chemistry and complexation of transition metals. 3.2.4 Inorganic chemistry and complexation of non-transition metals and metalloids3.3 Complexation of metals in solution; 3.3.1 Inorganic complexation; 3.3.2 An approach to determining metal(loid) speciation in solution; 3.3.3 The chemistry and speciation of metal-binding ligands; 3.3.4 The complexation of the major ions in solution; 3.3.5 Metal complexation with low molecular weight organic ligands; 3.3.6 Complexation to large molecular weight organic matter; 3.4 Trace metal interactions with the solid phase; 3.4.1 Precipitation and dissolution; 3.4.2 Adsorption of metals to aqueous solids. 3.4.3 Dissolved-particulate partition coefficients3.4.4 Adsorption isotherms; 3.4.5 A complexation-based model for adsorption; 3.5 Redox transformations and thermodynamic calculations; 3.5.1 Electrochemistry and the equilibrium constant; 3.5.2 The range in electrode potential and the stability of water; 3.5.3 Equilibrium calculations involving redox reactions; 3.5.4 Environmental considerations and controlling reactions; 3.6 Chapter summary; References; Problems; CHAPTER 4: Modeling approaches to estimating speciation and interactions in aqueous systems; 4.1 Introduction. Robert P. Mason. Includes bibliographical references and index. Trace elements Analysis Water Analysis Water chemistry SCIENCE Chemistry Organic Trace elements Analysis Water Analysis Water chemistry QD142 553.7 SCI013040 Mason, Robert P. (Robert Peter), 1956- Hoboken, NJ : John Wiley & Sons, 2013 (DLC) 2012038420 9781118274583 111827458X 9781118274590 1118274598 9781118274606 1118274601 9781118274576 1118274571 1405160489 9781405160483 9781299241558 1299241557 2013005424 http://onlinelibrary.wiley.com/book/10.1002/9781118274576 http://onlinelibrary.wiley.com/book/10.1002/9781118274576 DLC 130207 20171112085956.0 ocn827120262 eng