05886cam a2200805 i 4500 ocn827120262 OCoLC 20171112085956.0 m o d cr ||||||||||| 130207s2013 nju ob 001 0 eng 2013005424 9781118274583 (ePub) 111827458X (ePub) 9781118274590 (MobiPocket) 1118274598 (MobiPocket) 9781118274606 (Adobe PDF) 1118274601 (Adobe PDF) 9781118274576 (electronic bk.) 1118274571 (electronic bk.) 1405160489 9781405160483 9781299241558 (MyiLibrary) 1299241557 (MyiLibrary) 9781405160483 (hardback) AU@ 000050516386 AU@ 000053299832 DEBBG BV041828935 DEBBG BV041911239 DEBSZ 431348804 DKDLA 820120-katalog:000653834 NZ1 14873558 NZ1 15407490 (OCoLC)827120262 (OCoLC)829459896 (OCoLC)833300188 (OCoLC)849676876 (OCoLC)961609546 (OCoLC)962587323 (OCoLC)966248750 DLC eng rda pn DLC YDX N$T E7B DG1 YDXCP EBLCP IDEBK UBY CDX NOC UKDOC NHM OCLCF DEBSZ AU@ COO DEBBG OCLCQ LOA pcc MAIN QD142 NAT 038000 bisacsh NAT 030000 bisacsh 553.7 23 SCI013040 bisacsh Mason, Robert P. (Robert Peter), 1956- Trace metals in aquatic systems / Robert P. Mason. [electronic resource] Hoboken, NJ : John Wiley & Sons, 2013. 1 online resource. text txt rdacontent computer c rdamedia online resource cr rdacarrier Includes bibliographical references and index. Cover; Title page; Copyright page; Contents; Preface; About the companion website; CHAPTER 1: Introduction; 1.1 A historical background to metal aquatic chemistry; 1.2 Historical problems with metal measurements in environmental media; 1.3 Recent advances in aquatic metal analysis; References; Problems; CHAPTER 2: An introduction to the cycling of metals in the biosphere; 2.1 The hydrologic cycle; 2.2 An introduction to the global cycling of trace metal(loid)s; 2.2.1 The sources and cycling of metal(loid)s in the biosphere; 2.2.2 Metal(loid) partitioning and solubility in natural waters. 2.2.3 Human influence over metal(loid) fate and transport2.2.4 Trace metal(loid) inputs to the atmosphere; 2.2.5 Metal(loid)s in the terrestrial environment and freshwater ecosystems; 2.2.6 The transport of metal(loid)s to the ocean; 2.2.7 Trace metal(loid)s in ocean waters; 2.2.8 Trace metal(loid) inputs from hydrothermal vents; 2.3 Global cycles of some important trace metals; 2.3.1 The global cycles of cadmium, copper, and zinc; 2.3.2 The global cycle of mercury and lead; 2.4 Chapter summary; References; Problems. CHAPTER 3: Chemical thermodynamics and metal(loid) complexation in natural waters3.1 Thermodynamic background for understanding trace metal(loid) complexation; 3.1.1 The relationship between free energy and the equilibrium constant; 3.1.2 Ionic strength effects; 3.1.3 Thermodynamic equilibrium, kinetics and steady state; 3.2 Bonding, electronic configuration, and complex formation; 3.2.1 Ligand Field Theory; 3.2.2 Thermodynamic effects of orbital splitting; 3.2.3 Inorganic chemistry and complexation of transition metals. 3.2.4 Inorganic chemistry and complexation of non-transition metals and metalloids3.3 Complexation of metals in solution; 3.3.1 Inorganic complexation; 3.3.2 An approach to determining metal(loid) speciation in solution; 3.3.3 The chemistry and speciation of metal-binding ligands; 3.3.4 The complexation of the major ions in solution; 3.3.5 Metal complexation with low molecular weight organic ligands; 3.3.6 Complexation to large molecular weight organic matter; 3.4 Trace metal interactions with the solid phase; 3.4.1 Precipitation and dissolution; 3.4.2 Adsorption of metals to aqueous solids. 3.4.3 Dissolved-particulate partition coefficients3.4.4 Adsorption isotherms; 3.4.5 A complexation-based model for adsorption; 3.5 Redox transformations and thermodynamic calculations; 3.5.1 Electrochemistry and the equilibrium constant; 3.5.2 The range in electrode potential and the stability of water; 3.5.3 Equilibrium calculations involving redox reactions; 3.5.4 Environmental considerations and controlling reactions; 3.6 Chapter summary; References; Problems; CHAPTER 4: Modeling approaches to estimating speciation and interactions in aqueous systems; 4.1 Introduction. "The textbooks that currently exist do not deal with this particular subject in a comprehensive fashion, and therefore this book is being proposed to full this gap"-- Provided by publisher. Print version record and CIP data provided by publisher. Trace elements Analysis. Water Analysis. Water chemistry. SCIENCE Chemistry Organic. bisacsh Trace elements Analysis. fast (OCoLC)fst01153532 Water Analysis. fast (OCoLC)fst01171149 Water chemistry. fast (OCoLC)fst01171592 Electronic books. Electronic books. local Print version: Mason, Robert P. (Robert Peter), 1956- Trace metals in aquatic systems. Hoboken, NJ : John Wiley & Sons, 2013 9781405160483 (DLC) 2012038420 http://onlinelibrary.wiley.com/book/10.1002/9781118274576 Wiley Online Library ddc BK 206414 206414