06443cam a2200877Ia 4500 ocn801683685 OCoLC 20170612141629.0 m o d cr cn||||||||| 120725s2012 njua ob 001 0 eng d MYG eng pn MYG YDXCP E7B COO OCLCQ OCLCF OCLCA OCLCQ EBLCP N$T DG1 CDX OHI DEBSZ OCLCQ AZK DG1 798535399 809032254 927508439 961516108 962633705 9781118463215 (ebk.) 1118463218 (ebk.) 1118062760 (cloth) 9781118062760 (cloth) 9781118463185 (electronic bk.) 1118463188 (electronic bk.) 9781118062760 (cloth) 9786613722683 AU@ 000049858956 DEBBG BV040884621 DEBBG BV041829101 DEBSZ 431143501 DKDLA 820120-katalog:000599807 NZ1 14794755 NZ1 15042722 NZ1 15340995 (OCoLC)801683685 (OCoLC)798535399 (OCoLC)809032254 (OCoLC)927508439 (OCoLC)961516108 (OCoLC)962633705 372268 MIL TP1180.P68 M36 2012eb TEC 009010 bisacsh 668.4/234 23 MAIN Malpass, Dennis B. Introduction to industrial polypropylene : properties, catalysts, processes / Dennis B. Malpass and Elliot I. Band. Hoboken, N.J. : John Wiley & Sons ; Salem, Mass. : Co-published with Scrivener Pub., ©2012. 1 online resource (xxiv, 327 pages) : illustrations text txt rdacontent computer c rdamedia online resource cr rdacarrier data file rda Bibliography Includes bibliographical references and index. "This introductory text is an important resource for new engineers, chemists, students, and chemical industry personnel to understand the technical aspects of polypropylene which is the 2nd largest synthetics polymer in manufactured output."--Provided by publisher. Print version record. Introduction to Industrial Polypropylene: Properties, Catalysts, Processes; Contents; List of Tables; List of Figures; Preface; 1 Introduction to Polymers of Propylene; 1.1 Origins of Crystalline Polypropylene; 1.2 Basic Description of Polypropylene; 1.3 Types and Nomenclature of Polypropylene; 1.4 Molecular Weight of Polypropylene; 1.5 Transition Metal Catalysts for Propylene Polymerization; 1.6 Questions; References; 2 Polymer Characterization; 2.1 Introduction; 2.2 Polymer Tacticity; 2.2.1 Introduction; 2.2.2 Measurement of Polymer Microtacticity by 13C NMR; 2.2.3 Total Isotactic Index. 2.2.4 Total Xylene Insolubles; 2.3 Molecular Weight and Molecular Weight Distribution; 2.3.1 Introduction; 2.3.2 Gel Permeation Chromatography; 2.3.3 Intrinsic Viscosity; 2.3.4 Melt Flow Rate; 2.4 Polymer Bulk Density; 2.4.1 Introduction; 2.4.2 Measurement Method; 2.5 Particle Size Distribution and Morphology; 2.5.1 Introduction; 2.5.2 Measurement Method; 2.6 Questions; References; 3 Ziegler-Natta Catalysts; 3.1 A Brief History of Ziegler-Natta Catalysts; 3.2 Definitions and Nomenclature; 3.3 Characteristics of Ziegler-Natta Catalysts; 3.4 Early Commercial Ziegler-Natta Catalysts. 3.5 Supported Ziegler-Natta Catalysts; 3.6 Prepolymerized Ziegler-Natta Catalysts; 3.7 Mechanism of Ziegler-Natta Polymerization; 3.8 Questions and Exercises; References; 4 Propylene Polymerization Catalysts; 4.1 Introduction; 4.2 Zero Generation Ziegler-Natta Catalysts; 4.3 First Generation ZN Catalysts; 4.4 Second Generation ZN Catalysts; 4.5 Third Generation ZN Catalysts; 4.6 Fourth Generation ZN Catalysts; 4.7 Fifth Generation ZN Catalysts; 4.8 ZN Catalysts for Atactic Polypropylene; 4.9 Metallocenes and Other Single Site Catalysts; 4.10 Cocatalysts for ZN Catalysts. 4.11 Kinetics and ZN Catalyst Productivity; 4.12 Concluding Remarks; 4.13 Questions; References; 5 Aluminum Alkyls in Ziegler-Natta Catalysts; 5.1 Organometallic Compounds; 5.2 Characteristics of Aluminum Alkyls; 5.2.1 Basic Physical and Chemical Properties; 5.2.2 Hydride Content; 5.2.3 Other R3A1 Impurities; 5.2.4 Analysis of Aluminum Alkyls; 5.2.5 Impurities Resulting from Exposure to Minute Concentrations of Water and Oxygen; 5.2.6 Assays of Aluminum Alkyls; 5.2.7 Reactivity with Organic Substrates; 5.2.8 Reactivity with CO2 and CO; 5.2.9 Distillation; 5.2.10 Association of Aluminum Alkyls. 5.2.11 Storage Stability; 5.2.12 Thermal Stability; 5.3 Production of Aluminum Alkyls; 5.4 Reducing Agent for the Transition Metal; 5.5 Alkylating Agent for Creation of Active Centers; 5.6 Scavenger of Catalyst Poisons; 5.7 Chain Transfer Agent; 5.8 Safety and Handling of Aluminum Alkyls; 5.9 Questions; References; 6 Single Site Catalysts and Cocatalysts; 6.1 Introduction; 6.2 The Structures of Metallocenes and SSCs; 6.3 Non-Metallocene Polymerization Catalysts; 6.4 Cocatalysts for SSCs; 6.4.1 Aluminoxanes; 6.4.2 Organoboron Cocatalysts; 6.4.3 Activated Supports; 6.5 Supports for SSCs. 6.6 Characteristics of mPP. Polypropylene. Polymers. Polymerization. Engineering. Chemical engineering. TECHNOLOGY & ENGINEERING Chemical & Biochemical. bisacsh Polymerization. fast (OCoLC)fst01070576 Polymers. fast (OCoLC)fst01070588 Polypropylene. fast (OCoLC)fst01070781 Electronic books. Band, Elliot I. Wiley InterScience (Online service) Print version: Malpass, Dennis B. Introduction to industrial polypropylene. Hoboken, N.J. : John Wiley & Sons, 2012 (OCoLC)756596972 http://onlinelibrary.wiley.com/book/10.1002/9781118463215 Wiley Online Library Coutts Information Services COUT 22936744 EBL - Ebook Library EBLB EBL918624 ebrary EBRY ebr10579521 EBSCOhost EBSC 466220 YBP Library Services YANK 9007517 YBP Library Services YANK 9249306 YBP Library Services YANK 12672704 92 DG1 206046 206046